if I am running small business of printing and i am printing Student ID card and sale to Government school in this case GST liability is applicable on me when I am giving education related service and if yes, it is mentioned in which rule
You are to not giving educational services rather you are giving services to Educational Institutions.
So as per Notification 12/2017 CT rate :
Service Provided : to an educational institution, by way of :-
(i) transportation of students, faculty
and staff;
(ii) catering, including any mid-day
meals scheme sponsored by the Central Government State Government or UT;
(iii) security or cleaning or Housekeeping services performed in such educational institution;
(iv) services relating to admission to,
or conduct of examination by, such
institution; upto higher secondary:
As your Services not being cover above hence it is taxable