You can claim input tax credit of purchase bill of F.Y 2019-20 in GSTR 3b return up the return of September 2020 But you can't claim ITC of purchase relating to F.Y 2018-19 as the due date for claim of ITC is already expired. So, if your purchase bill are after 01 April 2019 than you can claim it in 3b return up to September 2020 return.
If the bill pertains to FY 2019-20, then the last date to claim ITC is the due date of filing September months Return ( 20th October 2020 ) or the date of filling Annual Return ( GSTR-9 ), whichever is "EARLIER."