The taxation of superannuation funds in India depends on the nature of the withdrawal (e.g., retirement, resignation, or death) and whether the fund is an "approved" superannuation fund under the Income Tax Act.
Taxation on Withdrawal
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At Retirement:
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You are generally allowed to withdraw up to one-third (33.3%) of the accumulated corpus as a tax-free lump sum.
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The remaining two-thirds must be utilized to purchase an annuity plan to provide a monthly pension. This transfer to an annuity is tax-free.
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The subsequent monthly pension received from the annuity is taxable as per your applicable income tax slab rates.
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At Resignation:
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If you withdraw the entire amount upon resigning before retirement age, the entire sum is generally taxable as "Income from Other Sources" or as salary, depending on the specific circumstances.
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However, if you transfer the balance to an approved superannuation fund of your new employer, it is not taxable at the time of transfer.
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On Death:
Regarding Your Specific Query
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Is it taxable? Yes, if you withdraw the amount upon resignation (and do not transfer it to a new employer's approved fund), it is considered taxable income.
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TDS: The 5% TDS deducted by your employer is an advance tax payment. You must report this income in your Income Tax Return (ITR). You will likely need to disclose it under "Income from Other Sources" (or as salary, depending on how your employer reported it) and claim the TDS already deducted.
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Section 10(13): This section relates to the exemption of payments from an approved superannuation fund. It is not a category for you to "show" the amount for tax-free status on its own, but rather a provision that defines the conditions under which such payments may be exempt (like on retirement or death). Since you are withdrawing upon resignation, this exemption generally does not apply to the lump sum.
Important Notes
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Combined Limit: Since the Finance Act 2020, there is a combined annual limit of ₹7.5 lakh for employer contributions to NPS, RPF, and Superannuation funds. Any employer contribution exceeding this aggregate amount in a financial year is treated as a taxable perquisite.
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Tax Regime: Note that tax rules can vary slightly between the Old and New Tax Regimes. Ensure you consult with a Chartered Accountant or tax professional to review your specific Form 16 and ITR filing requirements, especially since your employer has already deducted TDS.
Summary
Withdrawals from an approved superannuation fund are tax-free only under specific conditions (e.g., retirement, death, or transfer to a new employer's fund). Withdrawal upon resignation is generally fully taxable. The 5% TDS deducted is an advance payment; you should include the full amount as income in your ITR and claim the TDS credit.
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