If u r an individual (resident) paying tax u/s 44AD then u can't claim deduction u/s 80c . LIC premium paid u/s 80c can't claim. rent paid does not come under 80c - comes under 80gg if ur not in receipt of House rent allowance.
rent paid towards ur shop can deduct u/s 30. under the head " Income from business/ profession". but LIC premium paid can claim in deductions U/s 80 c .. but if u deposit / invest in new LIC policy in the year as annuity plan can claim as deduction. but I am not clear about the policy deposit
but LIC premium paid CAN'T claim in deductions u/s 80 c .... above spell mistake
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U/s 80C clause(xvii), you can claim tution fees paid to school, college or univeristy or any other educational institution. However any amount paid as donation cannot be claimed as a deduction under the said section 80C.