No, you won't be able to exchange all your cash that you have in your hand in one go. You can only receive upto Rs. 4000/person/day. Moreover if you have most of your transactions via cash only then for the time you can ask your client/customer to move towards online transaction system. This will help you make more safer and easier transactions fastly.
If you want to know more information on how to deal with cash crunch during demonetization, then you can read this infographic in detail:
https://blog.bajajfinserv.in/12-things-you-must-know-about-the-exchange-of-your-rs-500-and-rs-1000-notes/